9 research outputs found
Nanoparticle-doped electrospun fiber random lasers with spatially extended light modes
Complex assemblies of light-emitting polymer nanofibers with molecular
materials exhibiting optical gain can lead to important advance to amorphous
photonics and to random laser science and devices. In disordered mats of
nanofibers, multiple scattering and waveguiding might interplay to determine
localization or spreading of optical modes as well as correlation effects. Here
we study electrospun fibers embedding a lasing fluorene-carbazole-fluorene
molecule and doped with titania nanoparticles, which exhibit random lasing with
sub-nm spectral width and threshold of about 9 mJ cm^-2 for the absorbed
excitation fluence. We focus on the spatial and spectral behavior of optical
modes in the disordered and non-woven networks, finding evidence for the
presence of modes with very large spatial extent, up to the 100
micrometer-scale. These findings suggest emission coupling into integrated
nanofiber transmission channels as effective mechanism for enhancing spectral
selectivity in random lasers and correlations of light modes in the complex and
disordered material.Comment: 22 pages, 6 figure
Diverse regimes of mode intensity correlation in nanofiber random lasers through nanoparticle doping
Random lasers are based on disordered materials with optical gain. These
devices can exhibit either intensity or resonant feedback, relying on diffusive
or interference behaviour of light, respectively, which leads to either
coupling or independent operation of lasing modes. We study for the first time
these regimes in complex, solid-state nanostructured materials. The number of
lasing modes and their intensity correlation features are found to be
tailorable in random lasers made of light-emitting, electrospun polymer fibers
upon nanoparticle doping. By material engineering, directional waveguiding
along the length of fibers is found to be relevant to enhance mode correlation
in both intensity feedback and resonant feedback random lasing. The here
reported findings can be used to establish new design rules for tuning the
emission of nano-lasers and correlation properties by means of the
compositional and morphological properties of complex nanostructured materials.Comment: 30 pages, 10 figure
Sub-ms dynamics of the instability onset of electrospinning
Electrospun polymer jets are imaged for the first time at an ultra-high rate
of 10,000 frames per second, investigating the process dynamics, and the
instability propagation velocity and displacement in space. The polymer
concentration, applied voltage bias and needle-collector distance are
systematically varied, and their influence on the instability propagation
velocity and on the jet angular fluctuations analyzed. This allows us to unveil
the instability formation and cycling behavior, and its exponential growth at
the onset, exhibiting radial growth rates of the order of 10^3 s^-1. Allowing
the conformation and evolution of polymeric solutions to be studied in depth,
high-speed imaging at sub-ms scale shows a significant potential for improving
the fundamental knowledge of electrified jets, leading to obtain finely
controllable bending and solution stretching in electrospinning, and
consequently better designed nanofibers morphologies and structures.Comment: 23 pages, 9 figure
Electrostatic mechanophores in tuneable light-emitting piezo-polymer nanowires
Electromechanical coupling through piezoelectric polymer chains allows the
emission of organic molecules in active nanowires to be tuned. This effect is
evidenced by highly bendable arrays of counter-ion dye-doped nanowires made of
a poly(vinylidenefluoride) copolymer. A reversible redshift of the dye emission
is found upon the application of dynamic stress during highly accurate bending
experiments. By density functional theory calculations it is found that these
photophysical properties are associated with mechanical stresses applied to
electrostatically interacting molecular systems, namely to counterion-mediated
states that involve light-emitting molecules as well as charged regions of
piezoelectric polymer chains. These systems are an electrostatic class of
supramolecular functional stress-sensitive units, which might impart new
functionalities in hybrid molecular nanosystems and anisotropic nanostructures
for sensing devices and soft robotics.Comment: 32 pages, 18 figure
Atlante storico del diritto dei dati. Anni 2020-2022
Raccolta anni 2020-2022 della rubrica Diritto e nuove tecnologie pubblicata sulla rivista Persona e Mercat